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Election duty
depends on what you mean by "election duty"?
If you mean just going to vote, then you are not entitled to a day off.
If you are actually officially involved at a polling station, you may be entitled but you will have to make further enquiries about that.
Maybe try:
http://www.brussels.be/artdet.cfm/8233
http://verkiezingen.fgov.be/index.php?id=3292&L=0
Elections are usually held on a Sunday here, I assume to ensure most of the population can attend as voting is obligatory.
I've a vague memory that when my wife had to work at a polling station, without asking for it, she got an official 'attest' to give to her employer to get a day off work in lieu of the day she worked for the election.